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Beilstein J. Org. Chem. 2021, 17, 2765–2772, doi:10.3762/bjoc.17.186
Graphical Abstract
Figure 1: Biologically active 1-aminoisoquinolines.
Scheme 1: Comparison of our work with the previous approaches for the synthesis of 1-aminoisoquinolines.
Scheme 2: Substrate scope of anilines for the synthesis of 1-aminoisoquinolines (5a–m). Reaction conditions: 3...
Scheme 3: Substrate scope of 2-(2-oxo-2-phenylethyl)benzonitrile (3b–e) for the synthesis of 1-aminoisoquinol...
Scheme 4: Substrate scope of aliphatic amines for the synthesis of 1-aminoisoquinolines (5v–x), gram-scale sy...
Scheme 5: Proposed mechanism for the synthesis of 1-aminoisoquinoline 5a.